Why Lead-free?
- Legislation: European Union has established a phase-out
date of July 1, 2006 for Pb in electronic products with some exceptions.
- RoHS (Restriction on Hazardous Substances) and WEEE
(Waste Electrical and Electronic Equipment ) directives prohibit the
usage of Lead , Mercury, Cadmium, Hexavalent Chromium, PBB and PBDE.
- Customer requirement: Sony and other companies have
initiated a green procurement process which requires that all suppliers
provide green products before established deadlines.
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Definitions
Lead-free package
- Removal of lead (Pb) in package
- Lead-free package is ROHS compliance
Green package
- Removal of lead (Pb), antimony trioxide (Sb2O3) and brominated
flame-retarding compound from encapsulants and substrates
Maximum Levels Allowed
- Pb < 1000 ppm
- Halogens (Cl, Br) < 900 ppm
- Antimony < 900 ppm
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Package Materials Impacted
|
Package Type |
Material |
Reason |
|
Leadframe |
Lead Finish |
Removed Pb from solder |
|
|
Mold Compound |
Removed halogens, improve moisture sensitivity |
|
|
Die Attach Epoxy |
Improved adhesion and moisture resistance |
|
Area Array |
Die Attach Epoxy |
Improved adhesion and moisture resistance |
|
|
Substrate |
Removed halogens, improve moisture sensitivity |
|
|
Solder Mask |
Improved adhesion and moisture resistance |
|
|
Mold Compound |
Removed halogens, improve moisture sensitivity |
|
|
Solder Ball |
Removed Pb from solder ball |
|
Flip Chip |
Solder Bumps |
Removed Pb from solder |
Solutions
Terminations
- Lead plating from Sn-37Pb to Matted Sn.
- Pre-plated lead frame (PPF) with Ni/Pd/Au finish.
- Solder ball from Sn-37Pb to Sn-4.0Ag-0.5Cu (US) or Sn-3.0Ag-0.5Cu (Japan).
Mold Compound and Substrate
- Halogens, Sb2O3, and Phosphorous free.
- Moisture resistance for 260C reflow temp.
- Phosphorous free
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Lead-free Package Qualification
Reliability Test Items:
1. Precondition:
MSL Level III, 260 degree C
2. Temperature Cycle:
-65°~150°/1000 cycles
3. High Temp. Storage:
150/1000 hours
4. Temp Shock Test:
-65°~150°/100 cycles
5. Pressure Cooker Test:
121°/100% RH, 15 PSIG, 168 hours.
6. Other Tests:
Solderability, Lead finish composition, Whisker
test, etc
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Package Lead Free IR-Profile Samples
| Package Thickness |
Volume mm3 <350 |
Volume mm3 350 -2000 |
Volume mm3 >2000 |
| <1.6 mm |
260 +0 °C |
260 +0 °C |
260 +0 °C |
| 1.6 mm -2.5 mm |
260 +0 °C |
250 +0 °C |
245 +0 °C |
| ≥2.5 mm |
250 +0 °C |
245 +0 °C |
245 +0 °C |

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Nuvoton Lead-free Marking Symbol
We will print lead free symbol on bar code label to identification of Pb free
assemblies.

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Program Summary
-
Nuvoton's lead-free program started in 6/2000
-
Mass production of lead-free DRAM started in Oct. 2001.
-
Our major assembly subcontractors are ready for lead-free package qualification and production.
-
WEC's goal is to provide lead-free for all packages by Dec. 2005.
-
All products have been converted to lead-free package since Jul. 2006.
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F A Q
How does Nuvoton define “Pb-Free”, “ROHS compatible”
and “Green”?
- Pb-Free: Nuvoton's terms “ Lead-free” or ”Pb-free”
mean semiconductor products that are
compatible with current ROHS requirements for all 6 substances.
- Green: mean Pb-free and free of Bromine (Br) and Antimony (Sb) based flame
retardants.
How can I find out if a specific device is Pb-free or Green, or when
it will be?
- Nuvoton product content website shows the current production status, package
finish,
and Pb-free and Green status of the individual parts
Will Pb-free or Green devices be more expensive than Pb-based devices?
- Pricing is determined by product marketing. Conversion to Pb-free, in and
of itself,
is not planned to result in price changes.
If a device is converted to Pb-free, will Nuvoton continue to supply
the Pb-based part?
Will Nuvoton change the part numbers?
- Yes, product part number will be changed for lead-free part.
In what way would a Pb-free or Green device influence my board’s
functionalities or my application?
Are Pb-free parts compatible with a Pb-based soldering process?
- Our lead-frame based lead-free products are backward compatible with leaded
soldering process.
However, for BGA type lead-free products, it is not backward compatible with
leaded soldering process.
Solder joint reliability can be a concern.
What is being done to mitigate tin whisker growth?
- We have chosen matte tin as the lead finish for all lead-free products.
The package is
annealed within 24 hours at 150°C for 1 hour after lead plating.
This is the industry-accepted
method for mitigating tin whisker growth.
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